http://hdl.handle.net/11375/27629

Pan, Si (2018) Low-Cost Easy-to-Use Free Chlorine Sensor for Monitoring Drinking Water, MacSphere Open Access Dissertations and Theses, http://hdl.handle.net/11375/27629

In this thesis, low-cost free chlorine sensors for monitoring drinking water have been developed. The starting material, pencil lead, was modified using a ammonium carbamate solution. The main emphasis for this technology is the low cost, scalable and environmental friendly process. The resultant materials were highly sensitive to free chlorine. The second discovery was an advanced understanding of the unsteady state mass transfer during the sensing process, using the customly expanded Cottrell equation. This method could qualitatively indicated the absence of free chlorine, for applications where the removal of free chlorine is the goal. This method allowed better interpretation of transient data and simplified setup. The third discovery was the use of pulsed amperometric detection to detect free chlorine at a much higher sensitivity, while reducing the complexity of the setup, further reducing the cost. This method was based on the previous findings plus understanding of the reaction kinetics. The resultant sensors detected free chlorine with a detection of 0.0414 ppm, while the regulations require the free chlorine to be above 0.2 ppm. The response time was less than three seconds. The range of detection was up to around 20 ppm. The cost of materials for one sensor was less than ten dollars. The maintenance was minimal due to the lack of consumables. The operation could be as a meter or as a device in a large instrument. The target use of the sensors include small and distant communities, bottling industries, fruit and vegetable washing industries. The free chlorine sensing techniques can be readily expanded to biology, environment, and big data applications, based on the knowledge gained through the study.

https://macsphere.mcmaster.ca/bitstream/11375/27629/2/Pan_Si__2018October_PhD.pdf